749976 MSDS
2018-08-09
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Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 1 of 10 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Mad Farmer™ Oxygenator™ (Hydrogen Peroxide 35%) Product Description: A clear, colorless liquid having a sharp odor. An inorganic peroxide solution; Synonyms for Hydrogen Peroxide include Dihydrogen Dioxide, Hydroperoxide, Albone and Hioxyl. Information provided by: South Coast Horticultural Supply, Inc. 26895 Aliso Creek Road B685 Aliso Viejo, CA 92656 Telephone: (310) 947-6158 In case of emergency call: 911 For transportation Emergency call CHEMTREC: 800-424-9300 2. COMPOSITION & INFORMATION ON INGREDIENTS Component CAS# OSHA Hazard WT% Hydrogen Peroxide 7722-84-1 Oxidizer; Corrosive; Lung toxin; IARC-Suspected Carcinogen 20 to 50 3. HAZARDS IDENTIFICATION NPFA 704 DESIGNATION HAZARD RATING 4= Extreme 3= High 2= Moderate 1= Slight 0= Insignificant ACGIH TLV(TWA) STEL OSHA PEL(TWA) STEL 1 ppm (A3) 1 ppm None None Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 2 of 10 Emergency Overview: A clear, colorless liquid having a sharp odor. A strong oxidizer. Decompositions will release Oxygen, which will increase the explosive limits and the burning rate of flammable or combustible materials. The vapors, mists and liquid can cause severe irritation or burns to the eyes, skin and respiratory tract. Ingestion can cause severe damage to the gastrointestinal tract with possible stomach perforation. Ingestion of a large amount may cause convulsions, coma, possible cerebral edema and death. The NIOSH I.D.L.H. for Hydrogen Peroxide is: 75 ppm. POTENTIAL HEALTH EFFECTS Inhalation: Inhalation of vapors or mists may be severely irritating or corrosive to the nose, mouth throat, mucous membranes and lungs. Symptoms of exposure may include sneezing, coughing, choking, chest pain, shortness of breath and impairment of lung function. Some of these effects may be delayed until several hours after exposure. Eye Contact: Exposure to the vapors, mists or liquid can cause severe eye irritations or burns. Symptoms of exposure may include tearing, redness, swelling, a painful burning sensation and blurred vision. Direct contact with the liquid may cause corneal damage and impairment of vision. Skin Contact: Exposure to the mists or liquid can cause severe skin irritation or burns. Symptoms of exposure may include whitening or bleaching of the skin, swelling and eventually a painful tingling or burning sensation. Prolonged skin exposure may cause destruction of the dermis with impairment of the skin, at site of contact, to regenerate. No published data indicates this product is absorbed through the skin. Ingestion: Ingestion can cause severe irritation or burns to the mouth, throat and the entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding, tissue ulceration and possible stomach perforation. Ingestion of a large amount may be fatal. Chronic Hazards: Repeated exposure may cause bleaching of the hair and impairment of lung function. The IARC has classified Hydrogen Peroxide as a Group 3 carcinogen and the ACGIH as an A3 category “confirmed animal carcinogen with unknown relevance to humans”. Any increased risk of cancer is dependent upon the duration of exposure and/or the amount ingested. 4. FIRST AID MEASURES Inhalation: If inhaled, immediately move to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance, use the Holger Nielsen method (back pressure-arm lift) or proper respiratory device. If breathing is difficult, give oxygen. Call a physician. Eye Contact: In case of contact, immediately flush eyes with plenty of clean running water for at least 15 minutes, lifting the upper and lower lids occasionally. Remove contact lenses, if worn. Get medical attention immediately. Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 3 of 10 Skin Contact: In case of contact, immediately flush skin with plenty of clean running water for at least 15 minutes, while removing contaminated clothing and shoes. If burn or irritation occurs, call a physician. Ingestion: If swallowed, DO NOT induce vomiting. Get medical attention immediately. If victim is fully conscious, give plenty of water to drink. Never give anything by mouth to an unconscious person. Note to Physicians: The primary hazard of this product is the corrosivity effect on the eyes, skin and mucous membranes. If this product is ingested, it may be advisable to insert a gastric tube to relieve or prevent increased pressure that may result from the rapid evolution of Oxygen gas upon decomposition. Delayed pulmonary edema can occur several hours after initial exposure. 5. FIRE FIGHTING MEASURES Flashpoint and Method: This product does not flash. Flammable Limits (in air, % by volume): Lower: Not applicable Upper: Not applicable Autoignition Temperature: Not applicable. GENERAL HAZARD: The Uniform Fire Code health hazard classification for this product is Oxidizer, Class 2; and the health hazard is Corrosive. This product is not flammable, but thermal decomposition will release Oxygen, which will increase the explosive limits and the burning rate of flammable or combustible materials. This product may produce hazardous vapors, mists or decomposition products. Fire Fighting Instructions: Extinguishing Media: Flood with water. Use a water spray or fog to cool the containers exposed to the heat of a fire. Fire Fighting Equipment: Fire fighters should wear full protective equipment, including self-contained breathing apparatus. Hazardous Combustion Products: When heated to dryness and decomposition, it emits Hydrogen Peroxide, Oxygen gas and water vapor. 6. ACCIDENTAL RELEASE MEASURES Land Spill: Remove all combustible materials. Wearing recommended protective equipment and clothing, dike the spill and pick up the bulk of liquid using non-sparking tools, or absorb the liquid in sand or a non-combustible absorbent. Place in approved containers for disposal or satellite accumulation. CAUTION: Oxidizer wastes are not to be mixed with any other wastes, including other oxidizer wastes. Do not return this product to the original containers. Flush the spill area with water; collect the rinsates for disposal or sewer, as appropriate. Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 4 of 10 Water Spill: Wear recommended protective equipment and clothing if contact with hazardous material can occur. Stop or divert water flow. Dike contaminated water and remove for disposal and/or treatment. As appropriate, notify all downstream users of possible contamination. 7. HANDLING AND STORAGE Storage Temperature: Below 38°C (100°F) Storage Pressure: Ambient General: Store in a cool, dry, well-ventilated area away from sources of high intensity heat and incompatible materials or products. Do not expose to direct sunlight. Store in vented containers. This product can be potentially “explosive”, due to the rapid evolution of Oxygen gas, when contaminated with other chemicals, metals or even dirt. Avoid concentrating the Hydrogen Peroxide by the evaporation of the water. This product is a strong oxidizer and should be separated from all flammable or combustible products or materials, including wood. Do not get this product in eyes, on skin or on clothing. Wear recommended personnel protective equipment when handling this product. Do not breathe vapors, mists or aerosols. Use only with adequate ventilation. Keep the container tightly closed when not in use. Wash thoroughly after handling this product. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control Measures: Use a local or general, mechanical exhaust ventilation system capable of maintaining emissions, in the work area, below the OSHA-PEL or ACGIH-TLV levels. Recommended Personal Protective Equipment: Respirator: For exposure above the OSHA-PEL or ACGIH-TLV, but less than 10 ppm Hydrogen Peroxide, wear a NIOSH approved full facepiece or half mask air-purifying cartridge respirator equipped with a good particulate/mist cartridge, or a supplied air respirator. NIOSH recommendations for exposures: Greater than 10 ppm, but less than 25 ppm, use a supplied air respirator. Greater than 25 ppm, but less than 50 ppm, use a full facepiece, continuous flow, supplied air respirator. Greater than 50 ppm, but less than 75 ppm, use a full facepiece supplied air respirator or self-contained breathing apparatus (SCBA). Eyes: Wear chemical goggles (recommended by ANSI Z87.1-1979), unless a full facepiece respirator is worn. Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 5 of 10 Gloves: Wear Butyl Rubber, Nitrile, Viton, Responder, Tychem TK or Natural Rubber gloves when handling this product. Clothing and Equipment: Wear a Butyl Rubber, Nitrile or Natural Rubber apron or full protective clothing when handling this product. An eye wash station and safety shower should be available in the work area. Footwear: Wear Butyl Rubber, Nitrile or Natural Rubber boots. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Physical State: Odor: Odor Threshold: Clear, colorless Liquid Sharp No data available Molecular Formula: Molecular Weight: Boiling Point: Freezing/Melting Point: Specific gravity: H2O2 (in water) 34.02 (in water) Greater than 100°C (212°F) Less than 0°C (32°F) 1.069 to 1.195 @ 25°C Density (pounds/gallon): 8.92 to 9.97 Bulk Density(pounds/ft3): Vapor Pressure: Vapor density (air=1): Evaporation rate (n-Butyl Acetate=1): VOC Content: % Volatile: Solubility in H2O: Octanol/Water Partition Coefficient: pH (as is): pH (1% solution): Not applicable About 23 mm Hg @ 30°C No data available Less than 1 Not applicable 100% Complete No data available About (2.96-20%) to (1.34-50%) No data available 10.STABILITY AND REACTIVITY General: This product is stable and hazardous polymerization will not occur. Conditions to avoid: Hot storage, above 38°C (100°F). Incompatible Material: Caustics and strong alkali, all metals and metal salts, other oxidizers and all oxidizable substances. Hazardous Decomposition Products: When heated to dryness and decomposition, it emits Hydrogen Peroxide, Oxygen gas and water vapor. Sensitivity to Mechanical Impact: Sensitivity to Static Discharge: This product is NOT sensitive to mechanical impact. This product is NOT sensitive to static discharge. Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 6 of 10 11.TOXICOLOGICAL INFORMATION COMPONENTS: Hydrogen Peroxide Eye Contact: No data available Skin Contact: No data available Oral Rat LD50: 1,518 mg/kg (8-20% solution) Dermal Rabbit LD50: No data available Inhalation Rat LC50: 2 gm/m3/4 hours Human Data: Oral Man LDLo : 1,429 mg/kg (30% solution) Other Toxicological Data: Dermal Rat LD50 :4,060 mg/kg (90% solution) Carcinogenicity: Oral Mouse TDLO :622 gm/kg/2 years-Continuos; TumorigenicCarcinogenic by RTECS criteria; Gastrointestinal-Tumors (30% solution) Teratogenicity: No data available Mutagenicity: Human DNA damage; lymphocyte; 9 umol/Liter Synergistic Products: None reported Target Organs: Eyes, Skin, Mucous membranes, Lungs, Gastrointestinal tract and Central Nervous System Medical Conditions Aggravated Skin, Respiratory or By Exposure Gastrointestinal disorders 12.ECOLOGICAL INFORMATION Environmental Fate: This product is completely soluble in water and can affect the pH of water. No specific environmental fate data is available, but it is expected to readily break down to Oxygen and water, if introduced into the environment. Environmental Considerations: The aquatic toxicity for this product has not been determined. 13.DISPOSAL CONSIDERATIONS RCRA 40 CFR 261 Classification: Ignitable Waste U.S. EPA Waste Number/Description: D001 Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 7 of 10 If this product is disposed of as shipped, it meets the criteria of a hazardous waste as defined under 40 CFR 261 due to its ignitability. If this product becomes a waste, it will be a hazardous waste, which is subject to the Land Disposal Restrictions under 40 CFR 268 and must be managed accordingly. As a hazardous liquid waste, it must be disposed of in accordance with local, state, and federal regulations in a permitted hazardous waste treatment, storage, and disposal facility, by incineration. 14.TRANSPORTATION INFORMATION DOT Proper Shipping Name: Hydrogen Peroxide, aqueous solution Hazard Class: 5.1 (8) Primary Label: Oxidizer Primary/Subsidiary Placards: Oxidizer/Corrosive UN Number: Subsidiary Label(s): UN2014 Packing Group: II Packing Group: II Corrosive DOT RQ for Product: Not Reportable applicable Not listed Quantity (RQ): Marine No Pollutant: 2008 North American Emergency Response Guidebook No.: 140 TDG Proper Shipping HYDROGEN PEROXIDE, AQUEOUS SOLUTION Name: Hazard Class: 5.1 (8) UN UN2014 Number: Primary Label: Oxidizer Subsidiary Corrosive Label(s): Primary/Subsidiary Oxidizer Placards: TDG Reportable At least 50 kg or 50 Quantity liters (RQ):# TDG Not listed Schedule XII: Regulated RL for Product: Not applicable Not listed Limit (RL):## Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 8 of 10 Other Shipping Information: See Section 16 for additional information on shipping Hydrogen Peroxide, aqueous solutions. # Canadian Transportation of Dangerous Goods Regulations (TDGR), Part IX, Table 1, Quantities or levels for Immediate Reporting: releases of reportable quantities, RQ, that meet the definition of a “dangerous occurrence” (a threat to life, health, property, or the environment) must be reported to the appropriate authorities as outlined in TDGR 9.13(1) and 9.14(1). ## Reporting to Environment Canada is required for any releases exceeding the regulated limits, RL, of 9.2 materials (primary or secondary). The regulated limits are found in Schedule XIII of the TDGR. 15.REGULATORY INFORMATION COMPONENTS: Hydrogen Peroxide OSHA Target Organs: Eyes, Skin, Mucous membranes, Lungs, Gastrointestinal tract and central nervous System Carcinogenic Potential: Regulated by OSHA: No Listed on NTP Report: Listed by IARC: IARC group: ACGIH Appendix A: A1 Confirmed Human: A2 Suspected Human: U.S. EPA Requirements: Release Reporting CERCLA (40 CFR 302) Listed Substance: Reportable Quantity: Category: RCRA Waste No: Unlisted Substance: Reportable Quantity: Characteristic: RCRA Waste No: SARA TITLE III Section 302 & 303 (40 CFR 355): Listed Substance: Reportable Quantity: Planning Threshold: Section 311 & 312 (40 CFR 370) Hazard Categories (product): Fire: Sudden Release of Pressure: Reactive: No Yes Group 3 Yes (A3) Not applicable Not applicable Not listed Not applicable Not applicable Not applicable Yes 100 pounds Ignitability D001 Not listed Not applicable Not applicable Y N N Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 9 of 10 Acute Health: Y Chronic Health: N Planning Threshold: 10,000 pounds Section 313 (40 CFR 372): Listed Toxic chemical: Not listed Reporting Threshold: Not applicable U.S. TSCA Status Listed (40 CFR 710): Yes State Regulations State of California: Safe Drinking Water and Toxins Enforcement Act, 1986 (Proposition 65): Carcinogen: No Reproductive Toxin: No Other Regulations State Right to Know Laws: MA, NJ Canadian Regulations Product Information: Controlled Product: Yes WHMIS HAZARD Symbols: Oxidizing Material; Corrosive Material; Dangerously Reactive Material WHMIS Class & Division: C; E; F Ingredient Information: IDL Substance: Yes DSL or NDSL lists: DSL 16.OTHER INFORMATION EPA Registration number: Approved Product Uses: Not applicable Not applicable Special Notes: This product does not contain any substances, which the state of California has found to cause cancer and/or birth defects or other reproductive harm. Additional DOT Notes: 49 CFR 172.505(d)- “Hazardous materials that posses secondary hazards may exhibit secondary placards that correspond to the placards described in this part, even when not required by this part (see also 172.519(b)(4) of this subpart).” All containers holding a Hydrogen Peroxide solution that meets the DOT requirements as a hazardous material will have vented bungs and orientation arrows on two opposite sides that show which end must be up. Product Identifier: MAD FARMER™ Oxygenator™ Material Safety Data Sheet (MSDS) Page 10 of 10 Special Instructions: Store Mad Farmer™ Oxygenator™ in a cool, dry, well-ventilated area, out of direct sunlight and away from all incompatible materials or products. MSDS Revision Information: MSDS-O1 Updated April 26, 2012. This material Safety Data Sheet is provided as an information resource only. It should not be taken as a warranty or representation for which South Coast Horticultural Supply, Inc. assumes legal liability. While South Coast Horticultural Supply, Inc. believes the information contained herein is accurate and compiled from sources believed to be reliable, it is the responsibility of the user to investigate and verify its validity. The buyer assumes all responsibility of using and handling the product in accordance with applicable federal, state, and local regulations. All information appearing in this document was based on data provided by third party sources and was compiled to comply with the Federal Hazard Communication Standard and the California Hazardous Substances Information and Training Act. The information is believed to be accurate as of the Update, but is not warranted as being the final authority in the use of this product. This information does not purport to be legal or medical advice.
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