749976 MSDS
2018-08-09
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Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 1 of 10
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Mad Farmer™ Oxygenator™ (Hydrogen Peroxide 35%)
Product Description: A clear, colorless liquid having a sharp odor. An inorganic peroxide solution;
Synonyms for Hydrogen Peroxide include Dihydrogen Dioxide, Hydroperoxide, Albone and Hioxyl.
Information provided by: South Coast Horticultural Supply, Inc.
26895 Aliso Creek Road B685
Aliso Viejo, CA 92656
Telephone: (310) 947-6158
In case of emergency call: 911
For transportation Emergency call CHEMTREC: 800-424-9300
2. COMPOSITION & INFORMATION ON INGREDIENTS
ACGIH
OSHA
Component
CAS#
OSHA Hazard
WT%
TLV(TWA)
STEL
PEL(TWA)
STEL
Hydrogen
Peroxide
7722-84-1
Oxidizer; Corrosive; Lung
toxin; IARC-Suspected
Carcinogen
20 to 50
1 ppm
(A3)
None
1 ppm
None
3. HAZARDS IDENTIFICATION
NPFA 704
DESIGNATION
HAZARD RATING
4= Extreme
3= High
2= Moderate
1= Slight
0= Insignificant
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 2 of 10
Emergency Overview: A clear, colorless liquid having a sharp odor. A strong oxidizer. Decompositions
will release Oxygen, which will increase the explosive limits and the burning rate of flammable or
combustible materials. The vapors, mists and liquid can cause severe irritation or burns to the eyes,
skin and respiratory tract. Ingestion can cause severe damage to the gastrointestinal tract with
possible stomach perforation. Ingestion of a large amount may cause convulsions, coma, possible
cerebral edema and death. The NIOSH I.D.L.H. for Hydrogen Peroxide is: 75 ppm.
POTENTIAL HEALTH EFFECTS
Inhalation: Inhalation of vapors or mists may be severely irritating or corrosive to the nose, mouth
throat, mucous membranes and lungs. Symptoms of exposure may include sneezing, coughing,
choking, chest pain, shortness of breath and impairment of lung function. Some of these effects may
be delayed until several hours after exposure.
Eye Contact: Exposure to the vapors, mists or liquid can cause severe eye irritations or burns.
Symptoms of exposure may include tearing, redness, swelling, a painful burning sensation and blurred
vision. Direct contact with the liquid may cause corneal damage and impairment of vision.
Skin Contact: Exposure to the mists or liquid can cause severe skin irritation or burns. Symptoms of
exposure may include whitening or bleaching of the skin, swelling and eventually a painful tingling or
burning sensation. Prolonged skin exposure may cause destruction of the dermis with impairment of
the skin, at site of contact, to regenerate. No published data indicates this product is absorbed
through the skin.
Ingestion: Ingestion can cause severe irritation or burns to the mouth, throat and the entire
gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting,
diarrhea, abdominal pain, bleeding, tissue ulceration and possible stomach perforation. Ingestion of a
large amount may be fatal.
Chronic Hazards: Repeated exposure may cause bleaching of the hair and impairment of lung
function. The IARC has classified Hydrogen Peroxide as a Group 3 carcinogen and the ACGIH as an A3
category “confirmed animal carcinogen with unknown relevance to humans”. Any increased risk of
cancer is dependent upon the duration of exposure and/or the amount ingested.
4. FIRST AID MEASURES
Inhalation: If inhaled, immediately move to fresh air. If not breathing, give artificial respiration. Do
not use mouth-to-mouth method if victim ingested or inhaled the substance, use the Holger Nielsen
method (back pressure-arm lift) or proper respiratory device. If breathing is difficult, give oxygen. Call
a physician.
Eye Contact: In case of contact, immediately flush eyes with plenty of clean running water for at least
15 minutes, lifting the upper and lower lids occasionally. Remove contact lenses, if worn. Get medical
attention immediately.
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 3 of 10
Skin Contact: In case of contact, immediately flush skin with plenty of clean running water for at least
15 minutes, while removing contaminated clothing and shoes. If burn or irritation occurs, call a
physician.
Ingestion: If swallowed, DO NOT induce vomiting. Get medical attention immediately. If victim is fully
conscious, give plenty of water to drink. Never give anything by mouth to an unconscious person.
Note to Physicians: The primary hazard of this product is the corrosivity effect on the eyes, skin and
mucous membranes. If this product is ingested, it may be advisable to insert a gastric tube to relieve
or prevent increased pressure that may result from the rapid evolution of Oxygen gas upon
decomposition. Delayed pulmonary edema can occur several hours after initial exposure.
5. FIRE FIGHTING MEASURES
Flashpoint and Method: This product does not flash.
Flammable Limits (in air, % by volume): Lower: Not applicable Upper: Not applicable
Autoignition Temperature: Not applicable.
GENERAL HAZARD: The Uniform Fire Code health hazard classification for this product is Oxidizer,
Class 2; and the health hazard is Corrosive. This product is not flammable, but thermal decomposition
will release Oxygen, which will increase the explosive limits and the burning rate of flammable or
combustible materials. This product may produce hazardous vapors, mists or decomposition
products.
Fire Fighting Instructions: Extinguishing Media: Flood with water. Use a water spray or fog to
cool the containers exposed to the heat of a fire.
Fire Fighting Equipment: Fire fighters should wear full protective equipment, including self-contained
breathing apparatus.
Hazardous Combustion Products: When heated to dryness and decomposition, it emits Hydrogen
Peroxide, Oxygen gas and water vapor.
6. ACCIDENTAL RELEASE MEASURES
Land Spill: Remove all combustible materials. Wearing recommended protective equipment and
clothing, dike the spill and pick up the bulk of liquid using non-sparking tools, or absorb the liquid in
sand or a non-combustible absorbent. Place in approved containers for disposal or satellite
accumulation. CAUTION: Oxidizer wastes are not to be mixed with any other wastes, including other
oxidizer wastes. Do not return this product to the original containers. Flush the spill area with water;
collect the rinsates for disposal or sewer, as appropriate.
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 4 of 10
Water Spill: Wear recommended protective equipment and clothing if contact with hazardous
material can occur. Stop or divert water flow. Dike contaminated water and remove for disposal
and/or treatment. As appropriate, notify all downstream users of possible contamination.
7. HANDLING AND STORAGE
Storage Temperature: Below 38°C (100°F)
Storage Pressure: Ambient
General: Store in a cool, dry, well-ventilated area away from sources of high intensity heat and
incompatible materials or products. Do not expose to direct sunlight. Store in vented containers. This
product can be potentially “explosive”, due to the rapid evolution of Oxygen gas, when
contaminated with other chemicals, metals or even dirt. Avoid concentrating the Hydrogen Peroxide
by the evaporation of the water. This product is a strong oxidizer and should be separated from all
flammable or combustible products or materials, including wood.
Do not get this product in eyes, on skin or on clothing. Wear recommended personnel protective
equipment when handling this product. Do not breathe vapors, mists or aerosols. Use only with
adequate ventilation. Keep the container tightly closed when not in use. Wash thoroughly after
handling this product.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Measures: Use a local or general, mechanical exhaust ventilation system capable of
maintaining emissions, in the work area, below the OSHA-PEL or ACGIH-TLV levels.
Recommended Personal Protective Equipment:
Respirator: For exposure above the OSHA-PEL or ACGIH-TLV, but less than 10 ppm Hydrogen
Peroxide, wear a NIOSH approved full facepiece or half mask air-purifying cartridge respirator
equipped with a good particulate/mist cartridge, or a supplied air respirator.
NIOSH recommendations for exposures:
Greater than 10 ppm, but less than 25 ppm, use a supplied air respirator.
Greater than 25 ppm, but less than 50 ppm, use a full facepiece, continuous flow,
supplied air respirator.
Greater than 50 ppm, but less than 75 ppm, use a full facepiece supplied air respirator
or self-contained breathing apparatus (SCBA).
Eyes: Wear chemical goggles (recommended by ANSI Z87.1-1979), unless a full facepiece
respirator is worn.
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 5 of 10
Gloves: Wear Butyl Rubber, Nitrile, Viton, Responder, Tychem TK or Natural Rubber gloves
when handling this product.
Clothing and Equipment: Wear a Butyl Rubber, Nitrile or Natural Rubber apron or full
protective clothing when handling this product. An eye wash station and safety shower should
be available in the work area.
Footwear: Wear Butyl Rubber, Nitrile or Natural Rubber boots.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Clear, colorless
Bulk Density(pounds/ft3):
Not applicable
Physical State:
Liquid
Vapor Pressure:
About 23 mm Hg @ 30°C
Odor:
Sharp
Vapor density (air=1):
No data available
Odor Threshold:
No data available
Evaporation rate
(n-Butyl Acetate=1):
Less than 1
Molecular Formula:
H2O2 (in water)
VOC Content:
Not applicable
Molecular Weight:
34.02 (in water)
% Volatile:
100%
Boiling Point:
Greater than 100°C (212°F)
Solubility in H2O:
Complete
Freezing/Melting
Point:
Less than 0°C (32°F)
Octanol/Water
Partition Coefficient:
No data available
Specific gravity:
1.069 to 1.195 @ 25°C
pH (as is):
About (2.96-20%) to
(1.34-50%)
Density (pounds/gallon):
8.92 to 9.97
pH (1% solution):
No data available
10. STABILITY AND REACTIVITY
General: This product is stable and hazardous polymerization will not occur.
Conditions to avoid: Hot storage, above 38°C (100°F).
Incompatible Material: Caustics and strong alkali, all metals and metal salts, other oxidizers and all
oxidizable substances.
Hazardous Decomposition Products: When heated to dryness and decomposition, it emits Hydrogen
Peroxide, Oxygen gas and water vapor.
Sensitivity to Mechanical Impact: This product is NOT sensitive to mechanical impact.
Sensitivity to Static Discharge: This product is NOT sensitive to static discharge.
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 6 of 10
11. TOXICOLOGICAL INFORMATION
COMPONENTS:
Hydrogen Peroxide
Eye Contact:
No data available
Skin Contact:
No data available
Oral Rat LD50:
1,518 mg/kg (8-20% solution)
Dermal Rabbit LD50:
No data available
Inhalation Rat LC50:
2 gm/m3/4 hours
Human Data:
Oral Man LDLo : 1,429 mg/kg
(30% solution)
Other Toxicological Data:
Dermal Rat LD50 :4,060 mg/kg
(90% solution)
Carcinogenicity:
Oral Mouse TDLO :622 gm/kg/2
years-Continuos; Tumorigenic-
Carcinogenic by RTECS criteria;
Gastrointestinal-Tumors (30%
solution)
Teratogenicity:
No data available
Mutagenicity:
Human DNA damage;
lymphocyte; 9 umol/Liter
Synergistic Products:
None reported
Target Organs:
Eyes, Skin, Mucous membranes,
Lungs, Gastrointestinal tract and
Central Nervous System
Medical Conditions Aggravated
By Exposure
Skin, Respiratory or
Gastrointestinal disorders
12. ECOLOGICAL INFORMATION
Environmental Fate: This product is completely soluble in water and can affect the pH of water. No
specific environmental fate data is available, but it is expected to readily break down to Oxygen and
water, if introduced into the environment.
Environmental Considerations: The aquatic toxicity for this product has not been determined.
13. DISPOSAL CONSIDERATIONS
RCRA 40 CFR 261 Classification: Ignitable Waste
U.S. EPA Waste Number/Description: D001
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 7 of 10
If this product is disposed of as shipped, it meets the criteria of a hazardous waste as defined under 40
CFR 261 due to its ignitability. If this product becomes a waste, it will be a hazardous waste, which is
subject to the Land Disposal Restrictions under 40 CFR 268 and must be managed accordingly. As a
hazardous liquid waste, it must be disposed of in accordance with local, state, and federal regulations
in a permitted hazardous waste treatment, storage, and disposal facility, by incineration.
14. TRANSPORTATION INFORMATION
DOT Proper
Shipping
Name:
Hydrogen Peroxide, aqueous solution
Hazard Class:
5.1 (8)
UN
Number:
UN2014
Packing
Group:
II
Primary Label:
Oxidizer
Subsidiary
Label(s):
Corrosive
Primary/Subsidiary
Placards:
Oxidizer/Corrosive
DOT
Reportable
Quantity
(RQ):
Not listed
RQ for Product:
Not
applicable
Marine
Pollutant:
No
2008 North American Emergency Response Guidebook No.:
140
TDG Proper
Shipping
Name:
HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Hazard Class:
5.1 (8)
UN
Number:
UN2014
Packing
Group:
II
Primary Label:
Oxidizer
Subsidiary
Label(s):
Corrosive
Primary/Subsidiary
Placards:
Oxidizer
TDG
Reportable
Quantity
(RQ):#
At least 50 kg or 50
liters
TDG
Schedule XII:
Not listed
Regulated
Limit (RL):##
Not listed
RL for Product:
Not applicable
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 8 of 10
Other
Shipping
Information:
See Section 16 for additional information on shipping Hydrogen Peroxide, aqueous
solutions.
# Canadian Transportation of Dangerous Goods Regulations (TDGR), Part IX, Table 1, Quantities or levels for Immediate Reporting: releases of reportable quantities, RQ, that
meet the definition of a “dangerous occurrence” (a threat to life, health, property, or the environment) must be reported to the appropriate authorities as outlined in TDGR
9.13(1) and 9.14(1).
## Reporting to Environment Canada is required for any releases exceeding the regulated limits, RL, of 9.2 materials (primary or secondary). The regulated limits are found in
Schedule XIII of the TDGR.
15. REGULATORY INFORMATION
COMPONENTS:
Hydrogen Peroxide
OSHA Target Organs:
Eyes, Skin, Mucous membranes, Lungs, Gastrointestinal tract and
central nervous System
Carcinogenic Potential:
Regulated by OSHA:
No
Listed on NTP Report:
No
Listed by IARC:
Yes
IARC group:
Group 3
ACGIH Appendix A:
Yes (A3)
A1 Confirmed Human:
Not applicable
A2 Suspected Human:
Not applicable
U.S. EPA Requirements:
Release Reporting
CERCLA (40 CFR 302)
Listed Substance:
Not listed
Reportable Quantity:
Not applicable
Category:
Not applicable
RCRA Waste No:
Not applicable
Unlisted Substance:
Yes
Reportable Quantity:
100 pounds
Characteristic:
Ignitability
RCRA Waste No:
D001
SARA TITLE III
Section 302 & 303 (40 CFR 355):
Listed Substance:
Not listed
Reportable Quantity:
Not applicable
Planning Threshold:
Not applicable
Section 311 & 312 (40 CFR 370)
Hazard Categories (product):
Fire:
Y
Sudden Release of Pressure:
N
Reactive:
N
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 9 of 10
Acute Health:
Y
Chronic Health:
N
Planning Threshold:
10,000 pounds
Section 313 (40 CFR 372):
Listed Toxic chemical:
Not listed
Reporting Threshold:
Not applicable
U.S. TSCA Status
Listed (40 CFR 710):
Yes
State Regulations
State of California: Safe Drinking Water and Toxins Enforcement Act, 1986 (Proposition 65):
Carcinogen:
No
Reproductive Toxin:
No
Other Regulations
State Right to Know Laws:
MA, NJ
Canadian Regulations
Product Information:
Controlled Product:
Yes
WHMIS HAZARD Symbols:
Oxidizing Material; Corrosive Material; Dangerously Reactive
Material
WHMIS Class & Division:
C; E; F
Ingredient Information:
IDL Substance:
Yes
DSL or NDSL lists:
DSL
16. OTHER INFORMATION
EPA Registration number: Not applicable
Approved Product Uses: Not applicable
Special Notes:
This product does not contain any substances, which the state of California has found to cause cancer
and/or birth defects or other reproductive harm.
Additional DOT Notes:
49 CFR 172.505(d)- “Hazardous materials that posses secondary hazards may exhibit secondary
placards that correspond to the placards described in this part, even when not required by this part
(see also 172.519(b)(4) of this subpart).”
All containers holding a Hydrogen Peroxide solution that meets the DOT requirements as a hazardous
material will have vented bungs and orientation arrows on two opposite sides that show which end
must be up.
Product Identifier: MAD FARMER™ Oxygenator™
Material Safety Data Sheet (MSDS)
Page 10 of 10
Special Instructions:
Store Mad Farmer™ Oxygenator™ in a cool, dry, well-ventilated area, out of direct sunlight and away
from all incompatible materials or products.
MSDS Revision Information: MSDS-O1
Updated April 26, 2012.
This material Safety Data Sheet is provided as an information resource only. It should not be taken as a warranty or representation for which
South Coast Horticultural Supply, Inc. assumes legal liability. While South Coast Horticultural Supply, Inc. believes the information contained
herein is accurate and compiled from sources believed to be reliable, it is the responsibility of the user to investigate and verify its validity.
The buyer assumes all responsibility of using and handling the product in accordance with applicable federal, state, and local regulations.
All information appearing in this document was based on data provided by third party sources and was compiled to comply with the Federal
Hazard Communication Standard and the California Hazardous Substances Information and Training Act. The information is believed to be
accurate as of the Update, but is not warranted as being the final authority in the use of this product. This information does not purport to be
legal or medical advice.
