Bic Lighter SDS
2016-07-12
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Product Name: BIC Pocket Lighter Date Prepared: May 19, 2015 SAFETY DATA SHEET Version 6 SECTION 1 –IDENTIFICATION Product Name: Synonyms: Product Use: BIC Pocket Lighter None Thermoplastic casing with liquefied hydrocarbon fuel mixture for consumer use. Manufacturer/ Vendor Information: Supplier information: BIC Corporation One BIC Way, Suite 1 Shelton, CT 06484 USA (203) 783-2000 Emergency Telephone Number: (203) 783-2412 For Transportation Emergencies call CHEMTREC: (800)424-9300 SDS Contact: BIC Inc. 155 Oakdale Road Downsview, Ontario M3N 1W2 CANADA (416) 742-9173 x288 (Business hours) Product Safety Telephone Number: (203) 783-2124 SECTION 2 – HAZARD(S) IDENTIFICATION This product is a consumer product and is not subject to the requirements of OSHA HCS/HazCom 2012. Nonetheless, this SDS, including the hazard identification in accordance with HCS/HazCom 2012, is provided for the information of product users. Classification in Accordance with 29 CFR § 1910.1200: Signal Word: Hazard Statements: Flammable Gas – Category 1 Liquefied Gas Simple Asphyxiant Danger Extremely flammable gas Contains gas under pressure; may explode if heated May displace oxygen and cause rapid suffocation Symbols: Page 1 of 6 BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015 according to the HCS/HazCom 2012 (29 CFR § 1910.1200) Precautionary Statements: Prevention: Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Response: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Storage: Store in well-ventilated place. Protect from sunlight. Any Hazards Not Otherwise High vapor concentrations may cause headache, nausea, dizziness, drowsiness, Classified: incoordination and unconsciousness [Central Nervous System (CNS) depression]. Contact with liquefied gas may cause cold burns or frostbite to skin or eyes. Repeated inhalation of high concentrations of isobutene may cause weak cardiac sensitization. For more information refer to Section 11 of this SDS SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS Substance: CAS No. 75-28-5 Chemical Name Isobutane The following are components of the lighter casing material (an article), which are not expected to be hazardous during normal conditions of use: 25231-38-3 Polyoxymethylene thermoplastics (Acetal), may contain residual formaldehyde at <50 ppm. 32131-17-2 Polyamide type 66 thermoplastics (Nylon) SECTION 4 – FIRST-AID MEASURES Eyes: In the event of contact with liquefied isobutane, immediately and briefly, flush with lukewarm, gently flowing water for at least 15 minutes. If frostbite has occurred, DO NOT attempt to rewarm. Cover both eyes with a sterile dressing. DO NOT allow victim to drink alcohol or smoke. Quickly transport victim to an emergency care facility. Skin: In the event of contact with liquefied isobutane causing frostbite to the skin: DO NOT attempt to rewarm the affected area on site. DO NOT rub area or apply dry heat. Gently remove clothing or jewelry that may restrict circulation. Carefully cut around any clothing that sticks to the skin, and remove the rest of the garment. Loosely cover the affected area with a sterile dressing. DO NOT allow victim to drink alcohol or smoke. Quickly transport victim to emergency care facility. As quickly as possible, remove contaminated clothing, shoes, and leather goods (e.g., watchbands, belts) as the product is extremely flammable. Inhalation: This product is extremely flammable. Take proper precautions (e.g., remove any sources of ignition). If breathing has stopped, trained personnel should begin artificial respiration (AR) or, if the heart has stopped, cardiopulmonary resuscitation (CPR) immediately. Immediately transport victim to an emergency care facility. Ingestion: Ingestion of this product is unlikely since isobutane is a gas at room temperature. Most Important Symptoms and Effects, Both Acute and Delayed Symptoms/Injuries Inhalation of high concentrations can cause CNS effects and weak cardiac sensitization. after Inhalation: Symptoms/Injuries Direct contact with liquefied gas may cause cold burns/frostbite. after Skin Contact: Symptoms/Injuries Direct contact with liquefied gas may cause cold burns/frostbite and permanent eye after Eye Contact: damage. Symptoms/Injuries after Ingestion: Ingestion of this product is unlikely since isobutane is a gas at room temperature. Indication of Any Immediate Medical Attention and Special Treatment Needed BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015 according to the HCS/HazCom 2012 (29 CFR § 1910.1200) Treat symptomatically. SECTION 5 – FIRE-FIGHTING MEASURES Extinguishing Media: Suitable: Dry chemical powder and high-expansion foam Unsuitable: carbon dioxide, low expansion foam, water EXTREMELY FLAMMABLE. Will release gases that form flammable mixtures at or above the flash point. Isobutane is heavier than air and may travel along the ground or be moved by ventilation to sources of ignition far removed from the source of isobutane. Carbon monoxide, carbon dioxide, smoke and irritating vapors may be formed on combustion. Wear self-contained breathing apparatus and protective clothing to prevent inhalation and contact with skin and eyes. Conditions of Flammability: Hazardous Combustion Products: Special Firefighting Procedures: SECTION 6 – ACCIDENTAL RELEASE MEASURES Personal Precautions: Methods for Containment and Cleaning Up: Extremely flammable. Ventilate area. Avoid using sources of ignition in release area. Prevent material from entering confined spaces. Stop or reduce leak if you can do so without risk. Isolate area until gas has dispersed. SECTION 7 – HANDLING AND STORAGE Handling Precautions for Safety Handling: Storage Extremely flammable. Avoid inhalation and contact with eyes and skin. Wash thoroughly after handling this product if in contact with skin. Store in cool, dry, well-ventilated area. Protect from sunlight. Store away from incompatible and reactive materials (See Section 10). Keep container tightly closed. Store away from heat and sources of ignition. SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters Chemical Name CAS Number Exposure Limits Isobutane 75-28-5 ACGIH: (TLV-STEL) 1000 ppm (butane, all isomers) TLV Basis – Critical Effects: Central Nervous system impairment 3 NIOSH (REL-TWA) 800 ppm (1900 mg/m ) The selection of personal protective equipment varies, depending upon the conditions of use. Use equipment appropriate to your particular use pattern. Engineering Measures: For normal application, special ventilation is not necessary. Eye Protection: Not required under normal use conditions. Hand Protection: None necessary under normal use conditions. Skin and Body Protection: None necessary under normal use conditions. Respiratory Protection: None necessary under normal use conditions. ACGIH = American Conference of Governmental Industrial Hygienists NIOSH = National Institute for Occupational Safety and Health REL = Recommended Exposure Limit TLV = Threshold Limit Value TWA= Time-Weighted Average STEL = Short-Term Exposure Limit Page 3 of 6 BIC Pocket Lighter SAFETY DATA SHEET according to the HCS/HazCom 2012 (29 CFR § 1910.1200) SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Appearance & Physical State: Isobutane – Clear colorless liquefied gas. Plastic polymer casing – solid plastic material. Odor: Odor Threshold: pH: Melting Point: Boiling Point: Flash Point: Evaporation Rate: Flammability: Flammability Limits in Air Lower (LFL): Upper (UFL): Vapor Pressure: Vapor Density: Density/Specific Gravity: Solubility in Water: Octanol/ Water Partition Coefficient: Sweet petroleum odor (isobutane) and slight plastic odor (casing) Odor threshold is not available. Not applicable -138.3°C (-216.9°F) – Isobutane -11.7°C (11°F) – Isobutane -83°C (-117°F) (Open Cup) >>1 (immediately evaporates) (Ethyl ether=1) Extremely flammable gas Auto-ignition Temperature: Decomposition Temperature: Viscosity: 860°F (460°C) Closed Cup – Isobutane Not available Not applicable 1.8% by volume – Isobutane 8.4% by volume – Isobutane 31 PSIG @ 70°F (21°C) – Isobutane 2.006 @ 60°F (15.6°C) (air =1) – Isobutane 0.5626 @ 60°F (15.6°C) Very slightly soluble (0.008%) (isobutane). Insoluble (casing). Log P(OCT) = 2.76 – Isobutane SECTION 10 – STABILITY AND REACTIVITY Reactivity Chemical Stability: Possibility of Hazardous Reactions: Conditions to Avoid: Incompatible Materials: This product is stable under the normal conditions of use. Stable Will not undergo hazardous polymerization. Hazardous Decomposition Products: None expected under the normal conditions of use. Avoid heat sources, sparks or flames and static discharge. Avoid strong oxidizing agents and halogen compounds. Page 4 of 6 May 19, 2015 BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015 according to the HCS/HazCom 2012 (29 CFR § 1910.1200) SECTION 11 – TOXICOLOGICAL INFORMATION Routes of Entry: Skin contact, Inhalation, Eye contact, Skin Absorption, Ingestion (in liquefied form) Acute Toxicity Product data: Not available. Ingredient data: Chemical CAS# Route & Species Value Isobutane 75-28-5 Inhalation, mouse (male) LC50 368,000 ppm (36.8%) (4h) Inhalation, rat LC50 >13,023 ppm (1.3%) (4h) LC50 570,000 ppm (57%) (15 mins)* *LC50 values obtained with 15-minute exposure durations cannot be reliably converted to 4-hour exposures. Eye Irritation: Skin Irritation: Ingestion Effects: Inhalation Effects: Skin Sensitization: Respiratory Tract Sensitization: Not expected to be an eye irritant. Contact with liquefied isobutane may cause cold burns/frostbite and permanent eye damage. Not expected to be a primary skin irritant. Contact with liquefied isobutane may cause cold burns/frostbite. Not applicable. Not an expected route of entry. Inhalation of high concentrations can cause CNS effects and weak cardiac sensitization (to adrenaline). Contact with this product is not expected to cause skin sensitization, based upon the available data and the known hazards of the components. Contact with this product is not expected to cause respiratory tract sensitization, based upon the available data and the known hazards of the components. Chronic Toxicity Carcinogenicity: This product is not known to contain any components at >= 0.1% that have been shown to cause cancer. Therefore, based upon the available data and the known hazards of the components, this product is not expected to be a carcinogen. Mutagenicity: This product is not known to contain any components at >= 0.1% that have been shown to cause mutagenicity. Therefore, based upon the available data and the known hazards of the components, this product is not expected to be a mutagen. Reproductive Toxicity: This product is not known to contain any components at >= 0.1% that have been shown to cause reproductive toxicity. Therefore, based upon the available data and the known hazards of the components, this product is not expected to be a reproductive toxin. Teratogenicity/Embryotoxicity: This product is not known to contain any components at >= 0.1% that have been shown to cause teratogenicity and/or embryotoxicity. Therefore, based upon the available data and the known hazards of the components, this product is not expected to be a teratogen/embryotoxin. Other Chronic Effects: Exposure to isobutane is not known to cause chronic toxic effects of sufficient severity to threaten life or cause serious impairment. Page 5 of 6 BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015 according to the HCS/HazCom 2012 (29 CFR § 1910.1200) SECTION 12 – ECOLOGICAL INFORMATION Ecotoxicity: Persistence/ Degradability: Not Available Not Available Bioaccumulation: Mobility: Other Adverse Effects: Not Available Not Available Not Available SECTION 13 – DISPOSAL CONSIDERATIONS Waste Disposal Method: In accordance with local, provincial/territorial or federal guidelines and regulations. SECTION 14 – TRANSPORT INFORMATION Shipping name UN Hazard Class Number DOT (US) LIGHTERS DOT= Department of Transport 1057 2.1 PG -- SECTION 15 – REGULATORY INFORMATION OSHA Classification: (OSHA Hazard Communication Standard (29 CFR §1910.1200)) This product has been classified in accordance with the hazard criteria of the OSHA’s HCS/HazCom 2012 and the SDS contains all the information required by the 29 CFR § 1910.1200. Hazard Ratings Health: Flammability: Reactivity: NPCA/HMIS 1 4 0 NFPA 704 1 4 0 NPCA/HMIS – National Paint and Coatings Association/ Hazardous Materials Identification System NFPA – National Fire Protection Association 1. The components in this product are listed on the TSCA Inventory or are otherwise exempt from TSCA. 2. Some plastics in this product may form formaldehyde gases during their combustion. Formaldehyde is considered to be a carcinogen by the State of California (California Proposition 65) if exposure to it exceeds the No Significant Risk Level (NSRL)- Safe Harbor Level (40 micrograms/day). 3. ASTM F400-04 (Standard Consumer Safety Specification for Lighters). 4. ISO 9994 (Lighters – Safety Specification). 5. U.S. Safety Standard for Cigarette Lighters, 16 CFR Part 1210 (July 12, 1994). SECTION 16 – OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Preparation Date: May 19, 2015 Supersedes Date: May 6, 2015 Disclaimer: The information given is based on data currently available to us and is believed to be correct. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. No responsibility is assumed for injury or damage from the use of the products described herein. Page 6 of 6
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