Bic Lighter SDS
2016-07-12
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Product Name: BIC Pocket Lighter
SAFETY DATA SHEET
Date Prepared:
May 19, 2015
Version 6
SECTION 1 –IDENTIFICATION
Product Name:
BIC Pocket Lighter
Synonyms:
None
Product Use:
Thermoplastic casing with liquefied hydrocarbon fuel mixture for consumer
use.
Manufacturer/ Vendor Information:
Supplier information:
BIC Corporation
One BIC Way, Suite 1
Shelton, CT 06484
USA
(203) 783-2000
Emergency Telephone Number: (203) 783-2412
For Transportation Emergencies call CHEMTREC: (800)424-9300
BIC Inc.
155 Oakdale Road
Downsview, Ontario M3N 1W2
CANADA
(416) 742-9173 x288 (Business hours)
SDS Contact:
Product Safety
Telephone Number:
(203) 783-2124
SECTION 2 – HAZARD(S) IDENTIFICATION
This product is a consumer product and is not subject to the requirements of OSHA HCS/HazCom 2012.
Nonetheless, this SDS, including the hazard identification in accordance with HCS/HazCom 2012, is provided
for the information of product users.
Classification in
Accordance with 29 CFR §
1910.1200:
Flammable Gas – Category 1
Liquefied Gas
Simple Asphyxiant
Signal Word:
Danger
Hazard Statements:
Extremely flammable gas
Contains gas under pressure; may explode if heated
May displace oxygen and cause rapid suffocation
Symbols:
BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015
according to the HCS/HazCom 2012 (29 CFR § 1910.1200)
Precautionary Statements:
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Response:
Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
Eliminate all ignition sources if safe to do so.
Storage:
Store in well-ventilated place.
Protect from sunlight.
Any Hazards Not Otherwise
Classified:
High vapor concentrations may cause headache, nausea, dizziness, drowsiness,
incoordination and unconsciousness [Central Nervous System (CNS) depression].
Contact with liquefied gas may cause cold burns or frostbite to skin or eyes.
Repeated inhalation of high concentrations of isobutene may cause weak cardiac
sensitization.
For more information refer to Section 11 of this SDS
SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS
Substance:
CAS No.
Chemical Name
75-28-5
Isobutane
The following are components of the lighter casing material (an article), which are not expected to be hazardous
during normal conditions of use:
25231-38-3
Polyoxymethylene thermoplastics (Acetal), may contain residual formaldehyde at <50 ppm.
32131-17-2
Polyamide type 66 thermoplastics (Nylon)
SECTION 4 – FIRST-AID MEASURES
Eyes:
In the event of contact with liquefied isobutane, immediately and briefly, flush with
lukewarm, gently flowing water for at least 15 minutes. If frostbite has occurred, DO
NOT attempt to rewarm. Cover both eyes with a sterile dressing. DO NOT allow victim
to drink alcohol or smoke. Quickly transport victim to an emergency care facility.
Skin:
In the event of contact with liquefied isobutane causing frostbite to the skin: DO NOT
attempt to rewarm the affected area on site. DO NOT rub area or apply dry heat.
Gently remove clothing or jewelry that may restrict circulation. Carefully cut around any
clothing that sticks to the skin, and remove the rest of the garment. Loosely cover the
affected area with a sterile dressing. DO NOT allow victim to drink alcohol or smoke.
Quickly transport victim to emergency care facility. As quickly as possible, remove
contaminated clothing, shoes, and leather goods (e.g., watchbands, belts) as the
product is extremely flammable.
Inhalation:
This product is extremely flammable. Take proper precautions (e.g., remove any
sources of ignition). If breathing has stopped, trained personnel should begin artificial
respiration (AR) or, if the heart has stopped, cardiopulmonary resuscitation (CPR)
immediately. Immediately transport victim to an emergency care facility.
Ingestion:
Ingestion of this product is unlikely since isobutane is a gas at room temperature.
Most Important Symptoms and Effects, Both Acute and Delayed
Symptoms/Injuries
after Inhalation:
Inhalation of high concentrations can cause CNS effects and weak cardiac sensitization.
Symptoms/Injuries
after Skin Contact:
Direct contact with liquefied gas may cause cold burns/frostbite.
Symptoms/Injuries
after Eye Contact:
Direct contact with liquefied gas may cause cold burns/frostbite and permanent eye
damage.
Symptoms/Injuries
after Ingestion:
Ingestion of this product is unlikely since isobutane is a gas at room temperature.
Indication of Any Immediate Medical Attention and Special Treatment Needed
BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015
according to the HCS/HazCom 2012 (29 CFR § 1910.1200)
Page 3 of 6
Treat symptomatically.
SECTION 5 – FIRE-FIGHTING MEASURES
Extinguishing Media:
Suitable: Dry chemical powder and high-expansion foam
Unsuitable: carbon dioxide, low expansion foam, water
Conditions of Flammability:
EXTREMELY FLAMMABLE. Will release gases that form flammable mixtures at
or above the flash point. Isobutane is heavier than air and may travel along the
ground or be moved by ventilation to sources of ignition far removed from the
source of isobutane.
Hazardous Combustion
Products:
Carbon monoxide, carbon dioxide, smoke and irritating vapors may be formed on
combustion.
Special Firefighting
Procedures:
Wear self-contained breathing apparatus and protective clothing to prevent
inhalation and contact with skin and eyes.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Extremely flammable. Ventilate area. Avoid using sources of ignition in
release area.
Methods for Containment and
Cleaning Up:
Prevent material from entering confined spaces. Stop or reduce leak if you
can do so without risk. Isolate area until gas has dispersed.
SECTION 7 – HANDLING AND STORAGE
Handling
Precautions for Safety
Handling:
Extremely flammable. Avoid inhalation and contact with eyes and skin. Wash
thoroughly after handling this product if in contact with skin.
Storage
Store in cool, dry, well-ventilated area. Protect from sunlight. Store away from
incompatible and reactive materials (See Section 10). Keep container tightly closed.
Store away from heat and sources of ignition.
SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
Chemical Name
CAS Number
Exposure Limits
Isobutane
75-28-5
ACGIH: (TLV-STEL) 1000 ppm (butane, all isomers)
TLV Basis – Critical Effects: Central Nervous system impairment
NIOSH (REL-TWA) 800 ppm (1900 mg/m3)
The selection of personal protective equipment varies, depending upon the conditions of use. Use equipment
appropriate to your particular use pattern.
Engineering Measures:
For normal application, special ventilation is not necessary.
Eye Protection:
Not required under normal use conditions.
Hand Protection:
None necessary under normal use conditions.
Skin and Body Protection:
None necessary under normal use conditions.
Respiratory Protection:
None necessary under normal use conditions.
ACGIH = American Conference of Governmental Industrial Hygienists
NIOSH = National Institute for Occupational Safety and Health
REL = Recommended Exposure Limit
TLV = Threshold Limit Value
TWA= Time-Weighted Average
STEL = Short-Term Exposure Limit
BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015
according to the HCS/HazCom 2012 (29 CFR § 1910.1200)
Page 4 of 6
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Appearance & Physical State:
Isobutane – Clear colorless liquefied gas.
Plastic polymer casing – solid plastic material.
Odor:
Sweet petroleum odor (isobutane) and slight plastic odor (casing)
Odor Threshold:
Odor threshold is not available.
pH:
Not applicable
Melting Point:
-138.3°C (-216.9°F) – Isobutane
Boiling Point:
-11.7°C (11°F) – Isobutane
Flash Point:
-83°C (-117°F) (Open Cup)
Evaporation Rate:
>>1 (immediately evaporates) (Ethyl ether=1)
Flammability:
Extremely flammable gas
Flammability Limits in Air
Lower (LFL):
Upper (UFL):
1.8% by volume – Isobutane
8.4% by volume – Isobutane
Vapor Pressure:
31 PSIG @ 70°F (21°C) – Isobutane
Vapor Density:
2.006 @ 60°F (15.6°C) (air =1) – Isobutane
Density/Specific Gravity:
0.5626 @ 60°F (15.6°C)
Solubility in Water:
Very slightly soluble (0.008%) (isobutane). Insoluble (casing).
Octanol/ Water Partition
Coefficient:
Log P(OCT) = 2.76 – Isobutane
Auto-ignition Temperature:
860°F (460°C) Closed Cup – Isobutane
Decomposition Temperature:
Not available
Viscosity:
Not applicable
SECTION 10 – STABILITY AND REACTIVITY
Reactivity
This product is stable under the normal conditions of use.
Chemical Stability:
Stable
Possibility of Hazardous
Reactions:
Will not undergo hazardous polymerization.
Conditions to Avoid:
Avoid heat sources, sparks or flames and static discharge.
Incompatible Materials:
Avoid strong oxidizing agents and halogen compounds.
Hazardous Decomposition
Products:
None expected under the normal conditions of use.
BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015
according to the HCS/HazCom 2012 (29 CFR § 1910.1200)
Page 5 of 6
SECTION 11 – TOXICOLOGICAL INFORMATION
Routes of Entry:
Skin contact, Inhalation, Eye contact, Skin Absorption, Ingestion (in liquefied
form)
Acute Toxicity
Product data:
Not available.
Ingredient data:
Chemical
CAS#
Route & Species
Value
Isobutane
75-28-5
Inhalation, mouse
(male)
Inhalation, rat
LC50 368,000 ppm (36.8%) (4h)
LC50 >13,023 ppm (1.3%) (4h)
LC50 570,000 ppm (57%) (15 mins)*
*LC50 values obtained with 15-minute exposure durations cannot be reliably converted to 4-hour exposures.
Eye Irritation:
Not expected to be an eye irritant. Contact with liquefied isobutane may cause
cold burns/frostbite and permanent eye damage.
Skin Irritation:
Not expected to be a primary skin irritant. Contact with liquefied isobutane may
cause cold burns/frostbite.
Ingestion Effects:
Not applicable. Not an expected route of entry.
Inhalation Effects:
Inhalation of high concentrations can cause CNS effects and weak cardiac
sensitization (to adrenaline).
Skin Sensitization:
Contact with this product is not expected to cause skin sensitization, based upon
the available data and the known hazards of the components.
Respiratory Tract
Sensitization:
Contact with this product is not expected to cause respiratory tract sensitization,
based upon the available data and the known hazards of the components.
Chronic Toxicity
Carcinogenicity:
This product is not known to contain any components at >= 0.1% that have been
shown to cause cancer. Therefore, based upon the available data and the
known hazards of the components, this product is not expected to be a
carcinogen.
Mutagenicity:
This product is not known to contain any components at >= 0.1% that have been
shown to cause mutagenicity. Therefore, based upon the available data and the
known hazards of the components, this product is not expected to be a mutagen.
Reproductive Toxicity:
This product is not known to contain any components at >= 0.1% that have been
shown to cause reproductive toxicity. Therefore, based upon the available data
and the known hazards of the components, this product is not expected to be a
reproductive toxin.
Teratogenicity/Embryotoxicity:
This product is not known to contain any components at >= 0.1% that have been
shown to cause teratogenicity and/or embryotoxicity. Therefore, based upon the
available data and the known hazards of the components, this product is not
expected to be a teratogen/embryotoxin.
Other Chronic Effects:
Exposure to isobutane is not known to cause chronic toxic effects of sufficient
severity to threaten life or cause serious impairment.
BIC Pocket Lighter SAFETY DATA SHEET May 19, 2015
according to the HCS/HazCom 2012 (29 CFR § 1910.1200)
Page 6 of 6
SECTION 12 – ECOLOGICAL INFORMATION
Ecotoxicity:
Not Available
Persistence/ Degradability:
Not Available
Bioaccumulation:
Not Available
Mobility:
Not Available
Other Adverse Effects:
Not Available
SECTION 13 – DISPOSAL CONSIDERATIONS
Waste Disposal Method:
In accordance with local, provincial/territorial or federal guidelines and
regulations.
SECTION 14 – TRANSPORT INFORMATION
Shipping name
UN
Number
Hazard Class
PG
DOT (US)
LIGHTERS
1057
2.1
--
DOT= Department of Transport
SECTION 15 – REGULATORY INFORMATION
OSHA Classification: (OSHA Hazard Communication Standard (29 CFR §1910.1200))
This product has been classified in accordance with the hazard criteria of the OSHA’s HCS/HazCom 2012 and
the SDS contains all the information required by the 29 CFR § 1910.1200.
Hazard Ratings
NPCA/HMIS NFPA 704
Health: 1 1
Flammability: 4 4
Reactivity: 0 0
NPCA/HMIS – National Paint and Coatings Association/ Hazardous Materials Identification System
NFPA – National Fire Protection Association
1. The components in this product are listed on the TSCA Inventory or are otherwise exempt from TSCA.
2. Some plastics in this product may form formaldehyde gases during their combustion. Formaldehyde is
considered to be a carcinogen by the State of California (California Proposition 65) if exposure to it exceeds the
No Significant Risk Level (NSRL)- Safe Harbor Level (40 micrograms/day).
3. ASTM F400-04 (Standard Consumer Safety Specification for Lighters).
4. ISO 9994 (Lighters – Safety Specification).
5. U.S. Safety Standard for Cigarette Lighters, 16 CFR Part 1210 (July 12, 1994).
SECTION 16 – OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST
REVISION
Preparation Date: May 19, 2015
Supersedes Date: May 6, 2015
Disclaimer: The information given is based on data currently available to us and is believed to be correct. No
warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use
thereof. No responsibility is assumed for injury or damage from the use of the products described herein.
