Sikaflex EBT Clear

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SAFETY DATA SHEET
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

Sikaflex EBT+ Clear

SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier
Product name

: Sikaflex EBT+ Clear

1.2 Relevant identified uses of the substance or mixture and uses advised against
At present there is no complete information available on identified uses. When the data becomes available, it will be
integrated into the safety data sheet.
1.3 Details of the supplier of the safety data sheet
Manufacturer/Distributor

: Sika Limited
Watchmead Welwyn Garden City
Hertfordshire. AL7 1BQ
United Kingdom

Telephone no.:
Fax no.
e-mail address of person
responsible for this SDS
Emergency telephone number

: 01707 394444
: 01707 329129
: EHS@uk.sika.com
: +44 (0)1707 363899 (available during office hours).

1.4 Emergency telephone number
Supplier
Telephone number
: +44 (0)1707 363899 (available during office hours).

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition
: Mixture
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification
Environmental hazards

: R52/53
: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
See Section 16 for the full text of the R phrases or H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard symbol or symbols

:

Indication of danger

:

Risk phrases
Safety phrases

: R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
: S29- Do not empty into drains.

Hazardous ingredients
Supplemental label
elements

:
: Contains methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate, bis(1,2,2,6,
6-pentamethyl-4-piperidyl) sebacate. May produce an allergic reaction.

Date of issue

: 02.10.2013.

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SECTION 2: Hazards identification
Annex XVII - Restrictions
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
2.3 Other hazards
Other hazards which do
not result in classification

:

: Not available.

SECTION 3: Composition/information on ingredients
Substance/mixture

: Mixture
Classification

Product/ingredient name
Identifiers

%

trimethoxyvinylsilane
>=7, <25
RRN: 01-2119513215-52
EC: 220-449-8
CAS: 2768-02-7
methyl 1,2,2,6,6-pentamethyl-4-piperidyl
>=0.25, <1
sebacate
EC: 280-060-4
CAS: 82919-37-7
bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate >=0.25, <1
RRN: 01-2119491304-40
EC: 255-437-1
CAS: 41556-26-7

67/548/EEC

Type

Regulation (EC) No.
1272/2008 [CLP]

R10
Xn; R20

Flam. Liq. 3, H226
Acute Tox. 4, H332

[1]

R43
N; R50/53

[1]
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410

R43
N; R50/53

[1]
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410

See Section 16 for
the full text of the
R-phrases
declared above.

See Section 16 for the
full text of the H
statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a
workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures
4.1 Description of first aid measures
Eye contact
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation
: Get medical attention if adverse health effects persist or are severe.
Skin contact
Date of issue

: Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
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SECTION 4: First aid measures
Ingestion

: Do not induce vomiting unless directed to do so by medical personnel. Maintain an
open airway. Seek immediate medical attention.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact
: No known significant effects or critical
Inhalation
: No known significant effects or critical
Skin contact
: No known significant effects or critical
Ingestion
: No known significant effects or critical
Over-exposure signs/symptoms
Eye contact
: No specific data.
Inhalation
: No specific data.
Skin contact
: No specific data.
Ingestion

hazards.
hazards.
hazards.
hazards.

: No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician

: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
: No specific treatment.

Specific treatments

SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing
media

: Use dry chemical, CO₂, water spray (fog) or foam.

Unsuitable extinguishing
media

: None known.

5.2 Special hazards arising from the substance or mixture
Hazards from the
: In a fire or if heated, a pressure increase will occur and the container may burst.
substance or mixture
Hazardous thermal
decomposition products

: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides

5.3 Advice for firefighters
Special protective actions
for fire-fighters

Special protective
equipment for fire-fighters

Date of issue

: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. This material is harmful to aquatic organisms. Fire water
contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.

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SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency
: No action shall be taken involving any personal risk or without suitable training.
personnel
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also Section 8 for
additional information on hygiene measures.
6.2 Environmental
precautions

: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material.

6.3 Methods and materials for containment and cleaning up
Small spill
: Stop leak if without risk. Move containers from spill area. Absorb with an inert
material and place in an appropriate waste disposal container.
Large spill
: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
6.4 Reference to other
sections

: See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Protective measures
: Put on appropriate personal protective equipment (see Section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and
smoking. Do not breathe vapour or mist. Avoid contact with eyes, skin and clothing.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous.
Advice on general
occupational hygiene

: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section 8 for additional information on
hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental
contamination.
7.3 Specific end use(s)
Recommendations
Industrial sector specific
solutions

Date of issue

: Not available.
: Not available.

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SECTION 8: Exposure controls/personal protection
The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker or exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.
Recommended monitoring
procedures

: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.

DNELs/DMELs
No DELs available.
PNECs
No PECs available.
8.2 Exposure controls
Appropriate engineering
controls

: Good general ventilation should be sufficient to control worker exposure to airborne
contaminants. If this product contains ingredients with exposure limits, use process
enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure below any recommended or statutory limits.
Individual protection measures
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing.
Eye/face protection
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Skin protection
Hand protection
: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Reference number EN 374. Suitable for short time use or
protection against splashes: Butyl rubber/nitrile rubber gloves. (0,4 mm),
breakthrough time <30 min. Contaminated gloves should be removed. Suitable for
permanent exposure: Viton gloves (0.4 mm), breakthrough time >30 min.
Body protection

Other skin protection

Respiratory protection
Environmental exposure
controls

Date of issue

: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. Recommended: Use barrier skin cream.
: Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
: No special measures required.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

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SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state
Colour

: Paste.
: Clear.

Odour
Odour threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range

: Faint odour.
: Not available.
: Not available.
: Not available.
: Not available.

Flash point

: Not available.

Evaporation rate
Flammability (solid, gas)
Burning time

: Not available.
: Not available.
: Not applicable.

Burning rate

: Not applicable.

Upper/lower flammability or
explosive limits

: Not available.

Vapour pressure
Vapour density
Density

: Not available.
: Not available.
: ~1.05 g/cm³

Relative density
: Not available.
Solubility(ies)
: Insoluble in the following materials: water
Partition coefficient: n-octanol/ : Not available.
water
Auto-ignition temperature
Decomposition temperature
Viscosity

: Not available.
: Not available.
: Not available.

Explosive properties
Oxidising properties

: Not available.
: Not available.

9.2 Other information
No additional information.

SECTION 10: Stability and reactivity
10.1 Reactivity

: No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

: The product is stable.

10.3 Possibility of
hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

: No specific data.

10.5 Incompatible materials

: No specific data.

10.6 Hazardous
decomposition products

: Under normal conditions of storage and use, hazardous decomposition products
should not be produced.

Date of issue

: 02.10.2013.

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SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name

Result

trimethoxyvinylsilane

LC50 Inhalation Vapour
LD50 Dermal
LD50 Oral

Conclusion/Summary
Irritation/Corrosion
Conclusion/Summary

Species
Rat
Rat
Rat

Dose
16.8 mg/l
3540 mg/kg
7120 mg/kg

Exposure
4 hours
-

: Not available.
: Not available.

Sensitisation
Conclusion/Summary

: Not available.

Mutagenicity
Conclusion/Summary
Carcinogenicity
Conclusion/Summary
Reproductive toxicity
Conclusion/Summary
Teratogenicity
Conclusion/Summary

: Not available.
: Not available.
: Not available.
: Not available.

Information on the likely
routes of exposure

: Not available.

Potential acute health effects
Eye contact
Inhalation
Skin contact
Ingestion

:
:
:
:

May cause eye irritation.
May cause irritation.
May cause skin irritation.
Can cause gastrointestinal disturbances.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
effects
Potential delayed effects

: Not available.
: Not available.

Long term exposure
Potential immediate
: Not available.
effects
Potential delayed effects
: Not available.
Potential chronic health effects
Not available.
Conclusion/Summary

: Not available.

General
Carcinogenicity

: No known significant effects or critical hazards.
: No known significant effects or critical hazards.

Mutagenicity
Teratogenicity
Developmental effects

: No known significant effects or critical hazards.
: No known significant effects or critical hazards.
: No known significant effects or critical hazards.

Fertility effects
Other information

Date of issue

: No known significant effects or critical hazards.
: Not available.

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SECTION 12: Ecological information
12.1 Toxicity
Conclusion/Summary

: Not available.

12.2 Persistence and degradability
Conclusion/Summary
: Not available.
12.3 Bioaccumulative potential
Not available.
12.4 Mobility in soil
Soil/water partition
coefficient (KOC)

: Not available.

Mobility

: Not available.

12.5 Results of PBT and vPvB assessment
PBT
vPvB

: Not applicable.
: Not applicable.

12.6 Other adverse effects

: No known significant effects or critical hazards.

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Methods of disposal

Hazardous waste

: The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
: Yes.

European waste catalogue (EWC)
Waste code

Waste designation

08 04 09*

waste adhesives and sealants containing organic solvents or other dangerous substances

Packaging

: Completely emptied packaging or practically empty packaging containing dried/cured
residues, once relieved of all pressure can be disposed of as non-hazardous waste.
Packaging may still contain hazardous residues and disposal should undertaken by a
licensed waste contractor.

European waste catalogue
(EWC) (Packaging)

Date of issue

Any disposal practice must be in compliance with local and national laws and
regulations.
: packaging containing residues of or contaminated by dangerous substances

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SECTION 14: Transport information
ADR/RID - ADN
14.1 UN number

IMDG

IATA

Not regulated.

Not regulated.

Not regulated.

-

-

-

14.4 Packing group -

-

-

14.5
Environmental
hazards

No

No

No

Additional
information

-

-

-

14.2 UN proper
shipping name
14.3 Transport
hazard class(es)

14.7 Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code

: Not available.

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed (=> 0.1 %).
Substances of very high concern
None of the components are listed (=> 0.1 %).
Annex XVII - Restrictions
: Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
VOC content (EU)
: VOC (w/w): 0%
Other EU regulations
REACH Information:

: All substances contained in our Products are
- preregistered or registered by our upstream suppliers, and/or
- preregistered or registered by us, and/or
- excluded from the regulation, and/or
- exempted from the registration.

Europe inventory

: Not available.

References

: Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP
4)
Control of Substances Hazardous to Health Regulations 2002 (COSHH) (as
amended)
Health & Safety at Work Act 1974
The Environmental Protection (Duty of Care) Regulations 1991

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SECTION 15: Regulatory information
Guidance Publications

15.2 Chemical Safety
Assessment

The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2007
: Approved Code of Practice - Management of Health and Safety at Work, HSE
General Approved Code of Practice to COSHH Regulations, HSE.
: This product contains substances for which Chemical Safety Assessments are still
required.

SECTION 16: Other information
Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Full text of abbreviated H
: H226
Flammable liquid and vapour.
statements
H317
May cause an allergic skin reaction.
H332
Harmful if inhaled.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H412
Harmful to aquatic life with long lasting effects.
Full text of classifications
: Acute Tox. 4, H332
ACUTE TOXICITY: INHALATION - Category 4
[CLP/GHS]
Aquatic Acute 1, H400
ACUTE AQUATIC HAZARD - Category 1
Aquatic Chronic 1, H410 LONG-TERM AQUATIC HAZARD - Category 1
Aquatic Chronic 3, H412 LONG-TERM AQUATIC HAZARD - Category 3
Flam. Liq. 3, H226
FLAMMABLE LIQUIDS - Category 3
Skin Sens. 1, H317
SKIN SENSITIZATION - Category 1
Full text of abbreviated R
: R10- Flammable.
phrases
R20- Harmful by inhalation.
R43- May cause sensitisation by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Full text of classifications
[DSD/DPD]

: Xn - Harmful
N - Dangerous for the environment

History
Date of printing

: 02.10.2013.
: 02.10.2013.
Date of issue
Date of previous issue
: No previous validation.
Notice to reader
The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of
publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult
the product data sheet prior to any use and processing.

Date of issue

: 02.10.2013.

MSDS no. : 611826-1

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear

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: 02.10.2013.

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