Sikaflex EBT Clear
2015-05-08
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SAFETY DATA SHEET Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product name : Sikaflex EBT+ Clear 1.2 Relevant identified uses of the substance or mixture and uses advised against At present there is no complete information available on identified uses. When the data becomes available, it will be integrated into the safety data sheet. 1.3 Details of the supplier of the safety data sheet Manufacturer/Distributor : Sika Limited Watchmead Welwyn Garden City Hertfordshire. AL7 1BQ United Kingdom Telephone no.: Fax no. e-mail address of person responsible for this SDS Emergency telephone number : 01707 394444 : 01707 329129 : EHS@uk.sika.com : +44 (0)1707 363899 (available during office hours). 1.4 Emergency telephone number Supplier Telephone number : +44 (0)1707 363899 (available during office hours). SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Directive 1999/45/EC [DPD] The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification Environmental hazards : R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Hazard symbol or symbols : Indication of danger : Risk phrases Safety phrases : R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : S29- Do not empty into drains. Hazardous ingredients Supplemental label elements : : Contains methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate, bis(1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate. May produce an allergic reaction. Date of issue : 02.10.2013. MSDS no. : 611826-1 1/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 2/11 SECTION 2: Hazards identification Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles 2.3 Other hazards Other hazards which do not result in classification : : Not available. SECTION 3: Composition/information on ingredients Substance/mixture : Mixture Classification Product/ingredient name Identifiers % trimethoxyvinylsilane >=7, <25 RRN: 01-2119513215-52 EC: 220-449-8 CAS: 2768-02-7 methyl 1,2,2,6,6-pentamethyl-4-piperidyl >=0.25, <1 sebacate EC: 280-060-4 CAS: 82919-37-7 bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate >=0.25, <1 RRN: 01-2119491304-40 EC: 255-437-1 CAS: 41556-26-7 67/548/EEC Type Regulation (EC) No. 1272/2008 [CLP] R10 Xn; R20 Flam. Liq. 3, H226 Acute Tox. 4, H332 [1] R43 N; R50/53 [1] Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 R43 N; R50/53 [1] Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 See Section 16 for the full text of the R-phrases declared above. See Section 16 for the full text of the H statements declared above. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit and hence require reporting in this section. Type [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern Occupational exposure limits, if available, are listed in Section 8. SECTION 4: First aid measures 4.1 Description of first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Inhalation : Get medical attention if adverse health effects persist or are severe. Skin contact Date of issue : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. : 02.10.2013. MSDS no. : 611826-1 2/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 3/11 SECTION 4: First aid measures Ingestion : Do not induce vomiting unless directed to do so by medical personnel. Maintain an open airway. Seek immediate medical attention. 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact : No known significant effects or critical Inhalation : No known significant effects or critical Skin contact : No known significant effects or critical Ingestion : No known significant effects or critical Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion hazards. hazards. hazards. hazards. : No specific data. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. : No specific treatment. Specific treatments SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use dry chemical, CO₂, water spray (fog) or foam. Unsuitable extinguishing media : None known. 5.2 Special hazards arising from the substance or mixture Hazards from the : In a fire or if heated, a pressure increase will occur and the container may burst. substance or mixture Hazardous thermal decomposition products : Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides 5.3 Advice for firefighters Special protective actions for fire-fighters Special protective equipment for fire-fighters Date of issue : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. This material is harmful to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. : 02.10.2013. MSDS no. : 611826-1 3/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 4/11 SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also Section 8 for additional information on hygiene measures. 6.2 Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. 6.3 Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). 6.4 Reference to other sections : See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information. SECTION 7: Handling and storage 7.1 Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not breathe vapour or mist. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Advice on general occupational hygiene : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 7.3 Specific end use(s) Recommendations Industrial sector specific solutions Date of issue : Not available. : Not available. : 02.10.2013. MSDS no. : 611826-1 4/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 5/11 SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker or exposure or environmental releases. 8.1 Control parameters Occupational exposure limits No exposure limit value known. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances. DNELs/DMELs No DELs available. PNECs No PECs available. 8.2 Exposure controls Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Reference number EN 374. Suitable for short time use or protection against splashes: Butyl rubber/nitrile rubber gloves. (0,4 mm), breakthrough time <30 min. Contaminated gloves should be removed. Suitable for permanent exposure: Viton gloves (0.4 mm), breakthrough time >30 min. Body protection Other skin protection Respiratory protection Environmental exposure controls Date of issue : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Use barrier skin cream. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : No special measures required. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. : 02.10.2013. MSDS no. : 611826-1 5/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 6/11 SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state Colour : Paste. : Clear. Odour Odour threshold pH Melting point/freezing point Initial boiling point and boiling range : Faint odour. : Not available. : Not available. : Not available. : Not available. Flash point : Not available. Evaporation rate Flammability (solid, gas) Burning time : Not available. : Not available. : Not applicable. Burning rate : Not applicable. Upper/lower flammability or explosive limits : Not available. Vapour pressure Vapour density Density : Not available. : Not available. : ~1.05 g/cm³ Relative density : Not available. Solubility(ies) : Insoluble in the following materials: water Partition coefficient: n-octanol/ : Not available. water Auto-ignition temperature Decomposition temperature Viscosity : Not available. : Not available. : Not available. Explosive properties Oxidising properties : Not available. : Not available. 9.2 Other information No additional information. SECTION 10: Stability and reactivity 10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical stability : The product is stable. 10.3 Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. 10.4 Conditions to avoid : No specific data. 10.5 Incompatible materials : No specific data. 10.6 Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Date of issue : 02.10.2013. MSDS no. : 611826-1 6/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 7/11 SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Product/ingredient name Result trimethoxyvinylsilane LC50 Inhalation Vapour LD50 Dermal LD50 Oral Conclusion/Summary Irritation/Corrosion Conclusion/Summary Species Rat Rat Rat Dose 16.8 mg/l 3540 mg/kg 7120 mg/kg Exposure 4 hours - : Not available. : Not available. Sensitisation Conclusion/Summary : Not available. Mutagenicity Conclusion/Summary Carcinogenicity Conclusion/Summary Reproductive toxicity Conclusion/Summary Teratogenicity Conclusion/Summary : Not available. : Not available. : Not available. : Not available. Information on the likely routes of exposure : Not available. Potential acute health effects Eye contact Inhalation Skin contact Ingestion : : : : May cause eye irritation. May cause irritation. May cause skin irritation. Can cause gastrointestinal disturbances. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects Potential delayed effects : Not available. : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects Not available. Conclusion/Summary : Not available. General Carcinogenicity : No known significant effects or critical hazards. : No known significant effects or critical hazards. Mutagenicity Teratogenicity Developmental effects : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. Fertility effects Other information Date of issue : No known significant effects or critical hazards. : Not available. : 02.10.2013. MSDS no. : 611826-1 7/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 8/11 SECTION 12: Ecological information 12.1 Toxicity Conclusion/Summary : Not available. 12.2 Persistence and degradability Conclusion/Summary : Not available. 12.3 Bioaccumulative potential Not available. 12.4 Mobility in soil Soil/water partition coefficient (KOC) : Not available. Mobility : Not available. 12.5 Results of PBT and vPvB assessment PBT vPvB : Not applicable. : Not applicable. 12.6 Other adverse effects : No known significant effects or critical hazards. SECTION 13: Disposal considerations 13.1 Waste treatment methods Product Methods of disposal Hazardous waste : The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. : Yes. European waste catalogue (EWC) Waste code Waste designation 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances Packaging : Completely emptied packaging or practically empty packaging containing dried/cured residues, once relieved of all pressure can be disposed of as non-hazardous waste. Packaging may still contain hazardous residues and disposal should undertaken by a licensed waste contractor. European waste catalogue (EWC) (Packaging) Date of issue Any disposal practice must be in compliance with local and national laws and regulations. : packaging containing residues of or contaminated by dangerous substances : 02.10.2013. MSDS no. : 611826-1 8/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 9/11 SECTION 14: Transport information ADR/RID - ADN 14.1 UN number IMDG IATA Not regulated. Not regulated. Not regulated. - - - 14.4 Packing group - - - 14.5 Environmental hazards No No No Additional information - - - 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not available. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Annex XIV None of the components are listed (=> 0.1 %). Substances of very high concern None of the components are listed (=> 0.1 %). Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles VOC content (EU) : VOC (w/w): 0% Other EU regulations REACH Information: : All substances contained in our Products are - preregistered or registered by our upstream suppliers, and/or - preregistered or registered by us, and/or - excluded from the regulation, and/or - exempted from the registration. Europe inventory : Not available. References : Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP 4) Control of Substances Hazardous to Health Regulations 2002 (COSHH) (as amended) Health & Safety at Work Act 1974 The Environmental Protection (Duty of Care) Regulations 1991 Date of issue : 02.10.2013. MSDS no. : 611826-1 9/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear 02.10.2013 10/11 SECTION 15: Regulatory information Guidance Publications 15.2 Chemical Safety Assessment The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2007 : Approved Code of Practice - Management of Health and Safety at Work, HSE General Approved Code of Practice to COSHH Regulations, HSE. : This product contains substances for which Chemical Safety Assessments are still required. SECTION 16: Other information Indicates information that has changed from previously issued version. Abbreviations and acronyms : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Full text of abbreviated H : H226 Flammable liquid and vapour. statements H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Full text of classifications : Acute Tox. 4, H332 ACUTE TOXICITY: INHALATION - Category 4 [CLP/GHS] Aquatic Acute 1, H400 ACUTE AQUATIC HAZARD - Category 1 Aquatic Chronic 1, H410 LONG-TERM AQUATIC HAZARD - Category 1 Aquatic Chronic 3, H412 LONG-TERM AQUATIC HAZARD - Category 3 Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3 Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1 Full text of abbreviated R : R10- Flammable. phrases R20- Harmful by inhalation. R43- May cause sensitisation by skin contact. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Full text of classifications [DSD/DPD] : Xn - Harmful N - Dangerous for the environment History Date of printing : 02.10.2013. : 02.10.2013. Date of issue Date of previous issue : No previous validation. Notice to reader The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processing. Date of issue : 02.10.2013. MSDS no. : 611826-1 10/11 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) Sikaflex EBT+ Clear Date of issue : 02.10.2013. MSDS no. : 611826-1 02.10.2013 11/11 11/11
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