Sikaflex EBT Clear
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Sikaflex EBT+ Clear
SAFETY DATA SHEET
Product name
Sikaflex EBT+ Clear
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
:
1.1 Product identifier
1.3 Details of the supplier of the safety data sheet
1.2 Relevant identified uses of the substance or mixture and uses advised against
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.4 Emergency telephone number
Supplier
Telephone number
:
+44 (0)1707 363899 (available during office hours).
+44 (0)1707 363899 (available during office hours).
Emergency telephone number
Sika Limited
Watchmead Welwyn Garden City
Hertfordshire. AL7 1BQ
United Kingdom
Manufacturer/Distributor
01707 394444
Telephone no.:
Fax no.
01707 329129
e-mail address of person
responsible for this SDS
EHS@uk.sika.com
:
:
:
:
:
At present there is no complete information available on identified uses. When the data becomes available, it will be
integrated into the safety data sheet.
Classification
R52/53
:
:
Environmental hazards
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
See Section 11 for more detailed information on health effects and symptoms.
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition
:
Mixture
See Section 16 for the full text of the R phrases or H statements declared above.
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
2.2 Label elements
Supplemental label
elements
:
Contains methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate, bis(1,2,2,6,
6-pentamethyl-4-piperidyl) sebacate. May produce an allergic reaction.
Hazard symbol or symbols
Safety phrases
S29- Do not empty into drains.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Risk phrases
Hazardous ingredients
:
:
:
:
Indication of danger
:
Date of issue
:
1/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
2/11
SECTION 2: Hazards identification
:
Other hazards which do
not result in classification
Not available.
2.3 Other hazards
Annex XVII - Restrictions
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
:
trimethoxyvinylsilane
RRN: 01-2119513215-52
EC: 220-449-8
CAS: 2768-02-7
>=7, <25
R10
Xn; R20
Flam. Liq. 3, H226
Acute Tox. 4, H332
[1]
methyl 1,2,2,6,6-pentamethyl-4-piperidyl
sebacate
EC: 280-060-4
CAS: 82919-37-7
>=0.25, <1
R43
N; R50/53
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
[1]
bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate
RRN: 01-2119491304-40
EC: 255-437-1
CAS: 41556-26-7
>=0.25, <1
R43
N; R50/53
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
[1]
Substance/mixture
Mixture
Occupational exposure limits, if available, are listed in Section 8.
:
67/548/EEC
Product/ingredient name
Identifiers
See Section 16 for
the full text of the
R-phrases
declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a
workplace exposure limit and hence require reporting in this section.
SECTION 3: Composition/information on ingredients
%
Type
Regulation (EC) No.
1272/2008 [CLP]
Classification
See Section 16 for the
full text of the H
statements declared
above.
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Type
Skin contact
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
4.1 Description of first aid measures
Get medical attention if adverse health effects persist or are severe.
Inhalation
Eye contact
:
:
:
SECTION 4: First aid measures
Date of issue
:
2/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
3/11
SECTION 4: First aid measures
Do not induce vomiting unless directed to do so by medical personnel. Maintain an
open airway. Seek immediate medical attention.
Notes to physician
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Ingestion
:
:
Specific treatments
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:
:
:
Eye contact
:
No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
No specific treatment.
:
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. This material is harmful to aquatic organisms. Fire water
contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Hazardous thermal
decomposition products
Hazards from the
substance or mixture
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
Special protective
equipment for fire-fighters
Use dry chemical, CO₂, water spray (fog) or foam.
5.1 Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
SECTION 5: Firefighting measures
5.2 Special hazards arising from the substance or mixture
5.3 Advice for firefighters
Special protective actions
for fire-fighters
:
Date of issue
:
3/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
4/11
6.2 Environmental
precautions
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material.
Large spill
:
Stop leak if without risk. Move containers from spill area. Absorb with an inert
material and place in an appropriate waste disposal container.
Small spill
:
6.3 Methods and materials for containment and cleaning up
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
:
For emergency responders
:
6.4 Reference to other
sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also Section 8 for
additional information on hygiene measures.
:
:
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental
contamination.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Protective measures
:
Advice on general
occupational hygiene
:
7.2 Conditions for safe storage, including any incompatibilities
7.3 Specific end use(s)
Recommendations
:
:
Industrial sector specific
solutions
Not available.
Not available.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and
smoking. Do not breathe vapour or mist. Avoid contact with eyes, skin and clothing.
Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section 8 for additional information on
hygiene measures.
Date of issue
:
4/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
5/11
Recommended monitoring
procedures
Occupational exposure limits
If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Reference number EN 374. Suitable for short time use or
protection against splashes: Butyl rubber/nitrile rubber gloves. (0,4 mm),
breakthrough time <30 min. Contaminated gloves should be removed. Suitable for
permanent exposure: Viton gloves (0.4 mm), breakthrough time >30 min.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Eye/face protection
Respiratory protection
:
:
:
:
No exposure limit value known.
Skin protection
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. Recommended: Use barrier skin cream.
:
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
Good general ventilation should be sufficient to control worker exposure to airborne
contaminants. If this product contains ingredients with exposure limits, use process
enclosures, local exhaust ventilation or other engineering controls to keep worker
exposure below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing.
8.2 Exposure controls
Hygiene measures
:
No DELs available.
PNECs
No PECs available.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
DNELs/DMELs
Individual protection measures
Body protection
:
Other skin protection
Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
No special measures required.
The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker or exposure or environmental releases.
Date of issue
:
5/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
6/11
Not available.
Physical state
Melting point/freezing point
Initial boiling point and boiling
range
Vapour pressure
Relative density
Vapour density
Solubility(ies)
Paste.
Not available.
Not available.
Not available.
Not available.
Insoluble in the following materials: water
Faint odour.
Odour
pH
Clear.
Colour
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Viscosity
Not available.
Not available.
Odour threshold
Partition coefficient: n-octanol/
water
Upper/lower flammability or
explosive limits
Explosive properties
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Not available.
Oxidising properties
:
9.1 Information on basic physical and chemical properties
Appearance
9.2 Other information
Burning time
Not applicable.
Burning rate
Not applicable.
:
:
Decomposition temperature
:
Not available.
SECTION 9: Physical and chemical properties
Flammability (solid, gas)
:
Not available.
No additional information.
Density
:
~1.05 g/cm³
10.6 Hazardous
decomposition products
10.4 Conditions to avoid
No specific data.
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
The product is stable.
10.2 Chemical stability
No specific data.
:
:
:
10.5 Incompatible materials
:
10.3 Possibility of
hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
SECTION 10: Stability and reactivity
10.1 Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Date of issue
:
6/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
7/11
Potential chronic health effects
Potential acute health effects
Inhalation
:
May cause irritation.
Can cause gastrointestinal disturbances.
:
Ingestion
Skin contact
:
May cause skin irritation.
May cause eye irritation.
:
Eye contact
No known significant effects or critical hazards.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Acute toxicity
trimethoxyvinylsilane
LC50 Inhalation Vapour
Rat
16.8 mg/l
4 hours
LD50 Dermal
Rat
3540 mg/kg
-
LD50 Oral
Rat
7120 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Conclusion/Summary
:
Not available.
Not available.
Conclusion/Summary
:
Not available.
Carcinogenicity
Conclusion/Summary
:
Not available.
Mutagenicity
Conclusion/Summary
:
Not available.
Teratogenicity
Conclusion/Summary
:
Not available.
Reproductive toxicity
Conclusion/Summary
:
Not available.
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Irritation/Corrosion
Conclusion/Summary
:
Not available.
Sensitisation
Conclusion/Summary
:
Not available.
Not available.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Information on the likely
routes of exposure
:
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Long term exposure
Potential immediate
effects
Potential delayed effects
:
:
Potential immediate
effects
Potential delayed effects
:
:
Other information
:
Not available.
Not available.
Not available.
Not available.
Not available.
Date of issue
:
7/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
8/11
Mobility
Not available.
:
12.3 Bioaccumulative potential
12.6 Other adverse effects
No known significant effects or critical hazards.
Not available.
12.1 Toxicity
Conclusion/Summary
:
Not available.
12.2 Persistence and degradability
Conclusion/Summary
:
Not available.
PBT
:
Not applicable.
vPvB
:
Not applicable.
SECTION 12: Ecological information
12.4 Mobility in soil
Soil/water partition
coefficient (KOC)
Not available.
:
12.5 Results of PBT and vPvB assessment
:
European waste catalogue (EWC)
:
Methods of disposal
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Waste code
Waste designation
08 04 09*
waste adhesives and sealants containing organic solvents or other dangerous substances
The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste
:
Yes.
Packaging
:
Completely emptied packaging or practically empty packaging containing dried/cured
residues, once relieved of all pressure can be disposed of as non-hazardous waste.
Packaging may still contain hazardous residues and disposal should undertaken by a
licensed waste contractor.
Any disposal practice must be in compliance with local and national laws and
regulations.
European waste catalogue
(EWC) (Packaging)
:
packaging containing residues of or contaminated by dangerous substances
Date of issue
:
8/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
9/11
-
-
-
-
Not regulated.
-
-
Not regulated.
Not regulated.
-
-
-
SECTION 14: Transport information
ADR/RID - ADN
IMDG
IATA
14.1 UN number
14.2 UN proper
shipping name
14.3 Transport
hazard class(es)
14.4 Packing group
Additional
information
14.5
Environmental
hazards
14.7 Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code
No
No
No
:
Not available.
Other EU regulations
Not applicable.
Annex XVII - Restrictions
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
:
Europe inventory
:
References
:
Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP
4)
Control of Substances Hazardous to Health Regulations 2002 (COSHH) (as
amended)
Health & Safety at Work Act 1974
The Environmental Protection (Duty of Care) Regulations 1991
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
VOC content (EU)
:
VOC (w/w): 0%
All substances contained in our Products are
- preregistered or registered by our upstream suppliers, and/or
- preregistered or registered by us, and/or
- excluded from the regulation, and/or
- exempted from the registration.
REACH Information:
:
Not available.
Substances of very high concern
None of the components are listed (=> 0.1 %).
Annex XIV
None of the components are listed (=> 0.1 %).
Date of issue
:
9/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
10/11
SECTION 15: Regulatory information
15.2 Chemical Safety
Assessment
This product contains substances for which Chemical Safety Assessments are still
required.
:
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2007
Guidance Publications
:
Approved Code of Practice - Management of Health and Safety at Work, HSE
General Approved Code of Practice to COSHH Regulations, HSE.
R10- Flammable.
R20- Harmful by inhalation.
R43- May cause sensitisation by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Full text of abbreviated R
phrases
:
Xn - Harmful
N - Dangerous for the environment
:
Full text of classifications
[DSD/DPD]
Indicates information that has changed from previously issued version.
SECTION 16: Other information
Full text of abbreviated H
statements
:
Abbreviations and acronyms
:
ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
Full text of classifications
[CLP/GHS]
:
H226
Flammable liquid and vapour.
H317
May cause an allergic skin reaction.
H332
Harmful if inhaled.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H412
Harmful to aquatic life with long lasting effects.
Acute Tox. 4, H332
ACUTE TOXICITY: INHALATION - Category 4
Aquatic Acute 1, H400
ACUTE AQUATIC HAZARD - Category 1
Aquatic Chronic 1, H410
LONG-TERM AQUATIC HAZARD - Category 1
Aquatic Chronic 3, H412
LONG-TERM AQUATIC HAZARD - Category 3
Flam. Liq. 3, H226
FLAMMABLE LIQUIDS - Category 3
Skin Sens. 1, H317
SKIN SENSITIZATION - Category 1
02.10.2013.
History
Date of printing
Date of issue
02.10.2013.
Notice to reader
Date of previous issue
No previous validation.
:
:
:
The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of
publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult
the product data sheet prior to any use and processing.
Date of issue
:
10/11
611826-1
MSDS no.
:
02.10.2013.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)
Sikaflex EBT+ Clear
02.10.2013
11/11
Date of issue
:
11/11
611826-1
MSDS no.
:
02.10.2013.
